Researchers derive new theory on behavior of new class of materials

This work was done as part of Lopez-Pamies’s grant from the National Science Foundation (NSF) program, Designing Materials to Revolutionize and Engineer our Future (DMREF). In turn, DMREF is part of the multi-agency Materials Genome Initiative, which aims to pave the way for the discovery, manufacture and deployment of advanced materials.

“Ever since the discovery in the early 1900s that the addition of carbon black and silica nanoparticles to rubber resulted in a composite material with drastically enhanced properties, efforts have been continuously devoted to understanding when and how the addition of fillers to elastomers lead to materials with novel mechanical and physical properties,” Lopez-Pamies wrote. “The focus has been almost exclusively on solid filler inclusions.”

Recent theoretical and experimental results have revealed that instead of adding solid inclusions to elastomers, the addition of liquid inclusions may lead to an even more exciting new class of materials with the potential to enable a variety of new technologies. Some examples include elastomers filled with ionic liquids, liquid metals and ferrofluids, which exhibit unique combinations of mechanical and physical properties.

“The reason behind such novel properties is twofold,” wrote Lopez-Pamies. “On one hand, the addition of liquid inclusions to elastomers increases the overall deformability. This is in contrast to the addition of conventional fillers which, being made of stiff solids, decreases deformability. Additionally, the mechanics and physics of the interfaces separating a solid elastomer from embedded liquid inclusions, while negligible when the inclusions are large, may have a significant and even dominant impact on the macroscopic response of the material when the particles are small.

“Strikingly, the equations establish that these materials behave as solids, albeit solids with a macroscopic behavior that depends directly on the size of the liquid inclusions and the behavior of the elastomer/liquid interfaces. This allows access to an incredibly large range of fascinating behaviors by suitably tuning the size of the inclusions and the chemistry of the elastomer/liquid interfaces. One such remarkable behavior is “cloaking,” when the effect of the inclusions can be made to disappear.”

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